The refrigerants used in the air conditioning and refrigeration industries continue to evolve due to federal regulations based on the global warming potential (GWP) of refrigerants. Much of the attention has been focused on the new class of A2L refrigerants. However, small systems using class A3 refrigerants are also becoming common.
Class A2L refrigerants have moderate heat of combustion and propagate flame with low burning velocity. By contrast, class A3 refrigerants are highly flammable and explosive.
Refrigerants designated as class A3, along with their formulas and properties, can be located in the tables in the model mechanical codes and ASHRAE 34. The most common class A3 refrigerants are familiar compounds:
- R-290 (propane)
- R-600a (isobutane)
- R-1270 (propylene)
As a point of reference, liquefied petroleum (LP) gas is defined as a mixture of these three hydrocarbon gas compounds. However, readers should be aware of several key differences between a fuel gas and a refrigerant application, namely:
- Class A3 refrigerants do not contain odorants such as mercaptan. The odorant compounds used in fuel gas would be contaminants in a refrigeration system. An electronic detector designed for class A3 refrigerants can be used to detect a leak of these refrigerants.
- Mechanical refrigeration systems using class A3 refrigerants typically operate at pressures ranging from approximately 150 psi to 200 psi (1,000 kPa to1,400 kPa) as compared to low-pressure fuel gas distribution piping and appliance regulators that typically operate less than 1 psig (7 kPa).
- Mechanical refrigeration systems contain much lower quantities of gas compared to fuel-gas systems.